Endress+Hauser Chloromax CCS142D Manuale utente

Products Solutions Services

Operating Instructions

Chloromax CCS142D

Digital sensor with Memosens technology for

determining free chlorine

BA00419C/07/EN/15.17

71378188

AUTHORIZED DISTRIBUTOR:

InstrumentsAndControl.com

Houston, Texas USA

[email protected]

281-609-7170

Chloromax CCS142D Table of contents

Endress+Hauser 3

Table of contents

1 Document information ......... 4

1.1 Warnings ........................... 4

1.2 Symbols used ........................ 4

2 Basic safety instructions ....... 6

2.1 Requirements for the personnel ........ 6

2.2 Designated use ...................... 6

2.3 Occupational safety .................. 6

2.4 Operational safety ................... 7

2.5 Product safety ....................... 7

3 Product description ............. 8

3.1 Product design ....................... 8

4 Incoming acceptance and

product identification ......... 13

4.1 Incoming acceptance ................ 13

4.2 Product identification ................ 13

5 Installation .................... 16

5.1 Installation conditions ............... 16

5.2 Mounting the sensor ................ 18

5.3 Post-installation check ............... 19

6 Electrical connection .......... 20

6.1 Connecting the sensor ............... 20

6.2 Ensuring the degree of protection ..... 20

6.3 Post-connection check ............... 20

7 Commissioning ................ 22

7.1 Function check ..................... 22

7.2 Sensor polarization .................. 22

7.3 Calibrating the sensor ............... 22

8 Diagnostics and

troubleshooting ............... 24

9 Maintenance .................. 26

9.1 Maintenance schedule ............... 26

9.2 Maintenance tasks .................. 26

10 Repair .......................... 31

10.1 Spare parts ........................ 31

10.2 Return ............................ 31

10.3 Disposal ........................... 31

11 Accessories .................... 32

11.1 Device-specific accessories ............ 32

12 Technical data ................. 33

13 Installation and operation in

hazardous environment Class

I Div. 2 .......................... 36

Index ................................. 38

Document information Chloromax CCS142D

4 Endress+Hauser

1 Document information

1.1 Warnings

Structure of information Meaning

LDANGER

Causes (/consequences)

If necessary, Consequences of non-

compliance (if applicable)

‣Corrective action

This symbol alerts you to a dangerous situation.

Failure to avoid the dangerous situation will result in a fatal or serious injury.

LWARNING

Causes (/consequences)

If necessary, Consequences of non-

compliance (if applicable)

‣Corrective action

This symbol alerts you to a dangerous situation.

Failure to avoid the dangerous situation can result in a fatal or serious injury.

LCAUTION

Causes (/consequences)

If necessary, Consequences of non-

compliance (if applicable)

‣Corrective action

This symbol alerts you to a dangerous situation.

Failure to avoid this situation can result in minor or more serious injuries.

NOTICE

Cause/situation

If necessary, Consequences of non-

compliance (if applicable)

‣Action/note

This symbol alerts you to situations which may result in damage to property.

1.2 Symbols used

Symbol Meaning

Additional information, tips

Permitted or recommended

Not permitted or not recommended

Reference to device documentation

Reference to page

Reference to graphic

 Result of a step

Chloromax CCS142D Document information

Endress+Hauser 5

1.2.1 Symbols on the device

Symbol Meaning

Reference to device documentation

Basic safety instructions Chloromax CCS142D

6 Endress+Hauser

2 Basic safety instructions

2.1 Requirements for the personnel

Installation, commissioning, operation and maintenance of the measuring system may be

carried out only by specially trained technical personnel.

‣The technical personnel must be authorized by the plant operator to carry out the specified

activities.

‣The electrical connection may be performed only by an electrical technician.

‣The technical personnel must have read and understood these Operating Instructions and

must follow the instructions contained therein.

‣Measuring point faults may be repaired only by authorized and specially trained personnel.

Repairs not described in the Operating Instructions provided must be carried out only

directly at the manufacturer's site or by the service organization.

2.2 Designated use

Drinking water, process water and bathing water must be disinfected through the addition of

appropriate disinfectants such as chlorine gas or inorganic chlorine compounds. The dosing

quantity involved must be adapted to continuously fluctuating operating conditions. Too low

concentrations in the water could jeopardize the effectiveness of the disinfection process. Too

high concentrations can lead to signs of corrosion and have an adverse effect on taste, while

also generating unnecessary costs.

The sensor was specifically developed for this application and is designed for continuous

measurement of free chlorine in water. In conjunction with measuring and control equipment,

it allows optimum control of the disinfection process.

Use of the device for any purpose other than that described, poses a threat to the safety of

people and of the entire measuring system and is therefore not permitted.

The manufacturer is not liable for damage caused by improper or non-designated use.

2.2.1 Hazardous environment in accordance with cETLus NI Cl. I, Div. 2 1)

‣Please note the control drawing and the specified application conditions in the appendix of

these Operating Instructions and follow the instructions.

2.3 Occupational safety

As the user, you are responsible for complying with the following safety conditions:

• Installation guidelines

• Local standards and regulations

1) Only if connected to CM444R-EA* or CM448R-EA*

Chloromax CCS142D Basic safety instructions

Endress+Hauser 7

Electromagnetic compatibility

• The product has been tested for electromagnetic compatibility in accordance with the

applicable European standards for industrial applications.

• The electromagnetic compatibility indicated applies only to a product that has been

connected in accordance with these Operating Instructions.

2.4 Operational safety

Before commissioning the entire measuring point:

1. Verify that all connections are correct.

2. Ensure that electrical cables and hose connections are undamaged.

3. Do not operate damaged products, and protect them against unintentional operation.

4. Label damaged products as defective.

During operation:

‣If faults cannot be rectified:

products must be taken out of service and protected against unintentional operation.

2.4.1 Special instructions

‣Do not operate the sensors under process conditions where it is expected that osmotic

conditions will cause electrolyte components to pass through the membrane and into the

process.

Use of the sensor for its intended purpose in liquids with a conductivity of at least 10 nS/cm

can be classified as electrostatically safe.

2.5 Product safety

The product is designed to meet state-of-the-art safety requirements, has been tested, and

left the factory in a condition in which it is safe to operate. The relevant regulations and

European standards have been observed.

Product description Chloromax CCS142D

8 Endress+Hauser

3 Product description

3.1 Product design

The sensor consists of the following function units:

• Measuring chamber

– To protect the anode or cathode from the medium

– With a large volume of electrolyte for a long service life in combination with the large

anode and the small cathode

• Sensor shaft with

– Large anode

– Cathode embedded in plastic

– Temperature sensor

• Membrane cap with

– Robust PTFE membrane

– Special support grid between cathode and membrane for a specified and constant

electrolyte film and thus a relatively constant indication even at varying pressures and

flows

A0026479

 1 Sensor structure

1 Memosens plug-in head

2 O-ring

3 Large anode, silver/silver chloride

4 Gold cathode

5 Measuring chamber

6 Membrane cap with dirt-repellent membrane

7 Screw cap for securing the membrane cap

3.1.1 Measuring principle

Free chlorine is determined as hypochlorous acid according to the amperometric measuring

principle.

Chloromax CCS142D Product description

Endress+Hauser 9

The hypochlorous acid (HOCl) contained in the medium diffuses through the sensor

membrane and is reduced to chloride ions (Cl-) at the gold cathode. At the silver anode, silver

is oxidized to silver chloride. Electron donation at the gold cathode and electron acceptance at

the silver anode causes a current to flow which is in proportion to the concentration of free

chlorine in the medium at constant conditions.

The concentration of hypochlorous acid depends on the pH value. This dependency can be

compensated for by measuring the pH value in the flow assembly.

The transmitter uses the current signal to calculate the measured variable for concentration in

mg/l.

3.1.2 Effects on the measuring signal

pH value

pH-dependency

Molecular chlorine (Cl2) is present at pH values < 4. Consequently, hypochlorous acid (HOCl)

and hypochlorite (OCl– remain within the range of pH 4 to 11 as components of free chlorine.

As hypochlorous acid splits up (dissociates) with an increasing pH value to form hypochlorite

ions (OCl–) and hydrogen ions (H+), the amounts of the individual components of free

Product description Chloromax CCS142D

10 Endress+Hauser

effective chlorine change with the pH value. For example, if the proportion of hypochlorous

acid is 97 % at pH 6, it drops to approx. 3 % at pH 9.

100

45 6 7 8 9 10 11

100

OCl-

HOCl

A0002017

 2 Principle of pH compensation

A Measured value with pH compensation

B Measured value without pH compensation

C pH compensation

For amperometric measurement using the CCS142D chlorine sensor, only the amount of

hypochlorous acid is selectively measured. This works as a powerful disinfectant in a watery

solution. In contrast to this, hypochlorite is an extremely weak disinfectant. Therefore, when

used as a disinfectant at higher pH values, the effectiveness of chlorine is limited. As

hypochlorite ions cannot permeate the sensor membrane, the sensors do not record this

value.

pH compensation of chlorine sensor signal

To calibrate and verify the chlorine measuring system, a colorimetric reference measurement

must be carried out using the DPD method. Free chlorine reacts with diethyl-p-

phenylendiamine to form a red dye. The intensity of the red color increases proportionally to

the chlorine content. With the DPD method, the sample is buffered to a pH value of approx.

6.3. Therefore, the pH value of the sample is not included in the DPD measurement. Due to

the buffer function in the DPD method, all components of free effective chlorine are recorded

and thus the total free chlorine is measured.

If pH compensation is switched on in the transmitter, the sum of hypochlorous acid (HOCl)

and hypochlorite corresponding to the DPD measurement is calculated from the chlorine

Altri manuali per Chloromax CCS142D

Indice

Altri manuali Endress+Hauser Accessori

Endress+Hauser

Endress+Hauser Memosens COS51E Manuale utente

Endress+Hauser

Endress+Hauser Proline 100 Modbus RS485 Specifiche tecniche

Endress+Hauser

Endress+Hauser CCS140 Manuale utente

Endress+Hauser

Endress+Hauser Oxymax COS22 Series Manuale utente

Endress+Hauser

Endress+Hauser Memosens COS81E Specifiche tecniche

Endress+Hauser

Endress+Hauser Turbimax CUS51D Manuale

Endress+Hauser

Endress+Hauser Soliwave FQR56 Manuale utente

Endress+Hauser

Endress+Hauser Deltabar S FMD 77 Manuale

Endress+Hauser

Endress+Hauser CCS50D Manuale utente

Endress+Hauser

Endress+Hauser CUS 5 Manuale utente

Endress+Hauser

Endress+Hauser Proline 300 Specifiche tecniche

Endress+Hauser

Endress+Hauser OUSAF44 Manuale utente

Endress+Hauser

Endress+Hauser Liquiphant Manuale utente

Endress+Hauser

Endress+Hauser Proline Promag 50 Manuale utente

Endress+Hauser

Endress+Hauser NAR 300 Specifiche tecniche

Endress+Hauser

Endress+Hauser Oxymax W COS61 Manuale utente

Endress+Hauser

Endress+Hauser OxyMax W COS 71 Manuale utente

Endress+Hauser

Endress+Hauser Liquiphant M FTL51C Manuale utente

Endress+Hauser

Endress+Hauser Oxymax COS22D Manuale utente

Endress+Hauser

Endress+Hauser Deltapilot M FMB50 Specifiche tecniche

Endress+Hauser

Endress+Hauser Oxymax H COS21 Manuale utente

Endress+Hauser

Endress+Hauser Memosens COL37E Manuale utente

Endress+Hauser

Endress+Hauser NAR 300 Manuale utente

Endress+Hauser

Endress+Hauser Oxymax COS61 Manuale utente

Manuali Accessori popolari di altre marche

Hillco

Hillco 2810 Manuale utente

Siemens

Siemens QSA2700D Manuale dell'operatore

Contours

Contours ZY024 Manuale utente

Saivod

Saivod VS621 Manuale utente

Virtuox

Virtuox VirtuCLEAN 2.0 Manuale utente

SCE

SCE ENVIRO-THERM SCE-TE170B24VSS Manuale utente

Z-Wave

Z-Wave HSD-200Z Manuale utente

turck

turck FMX-IM-2UPLI63FX Manuale utente

Decagon Devices

Decagon Devices 10HS Manuale utente

UPPAbaby

UPPAbaby Cup Holder Manuale utente

Elko

Elko SmartSensor Leakage Wireless Manuale utente

Grizzly

Grizzly H8371 Manuale utente

Panasonic

Panasonic HG-T Series Manuale utente

IFM Electronic

IFM Electronic Efector 250 Series Guida di riferimento

DigiDesign

DigiDesign 888/24 I/O Manuale utente

PROZIS

PROZIS QUAY Manuale utente

patagonia

patagonia PSI Vest Manuale utente

SFC Energy

SFC Energy EFOY GO! Manuale utente